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Bushels of Buckyballs Found in Space

PostPosted: Sun Oct 31, 2010 3:20 pm
by seemslikeadream
BUSHELS OF BUCKYBALLS FOUND IN SPACE
The cages of carbon may be the FedEx of space, transporting other molecules and atoms through the cosmos.
By Irene Klotz
Thu Oct 28, 2010 12:45 PM ET
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Astronomers find buckyballs, hollow spheres of carbon, in four planetary nebulae and in interstellar space.
Buckyballs can travel between the stars, possibly transporting atoms and small molecules.
Meteorites that crashed into Earth have been found with buckyballs holding gases from beyond the solar system.
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The buckyballs were found in a dying star, called a planetary nebula, within the nearby galaxy, the Small Magellanic Cloud.

Strong cages of carbon, known as buckyballs, have been found not only in the exploded remains of stars, but also in interstellar space, raising the prospect that they may be the packaging to transport other molecules and atoms through the galaxy.

It was just three months ago that scientists first announced they'd found the 60-packs of carbon molecules, known as buckminsterfullerens, in a planetary nebula, the death shroud of an exploded star.

This week, astronomers report four more sightings of buckyballs in planetary nebula, including one located beyond the Milky Way in the Small Magellanic Cloud, a neighboring galaxy about 210,000 light-years away.

Scientists are at a loss to explain how buckyballs can exist in such hydrogen-rich environments. In laboratory studies, hydrogen nudges carbon molecules into chains and other shapes, preventing them from forming tiny hollow spheres that resemble geodesic domes, like the structure at Disney World's Epcot theme park.

Buckyballs, named after American architect and dome-lover Buckminster Fuller, are the third form of solid carbon, after diamond and graphite.

The most widely known buckyball consists of 60 carbon atoms arranged by pentagons and hexagons into a hollow molecular cage one-billionth of a meter wide. They can grow quite complex, with cages holding cages, holding cages, like layers of an onion.

"In nature, you need a lot of carbon atoms to see fullerenes. The importance of finding them in space is that it shows they occur in nature, but it's not super common," Letizia Stanghellini, with the National Optical Astronomy Observatory in Tucson, Ariz., told Discovery News.

Stanghellini's team looked at 250 targets with NASA's Spitzer infrared space telescope and found buckyballs in four of them, though the planetary nebula in the Small Magellanic Cloud had quite a lot of them -- about the mass of 15 Earth moons.

The strength and resilience of buckyballs -- and the fact that they're hollow -- make them a suitable container for holding single atoms or small molecules. Astronomers point to meteorites where buckyballs have been found holding gases that don't match what's found in our solar system, as an example.

"It really was surprising to find them in interstellar medium. That was not expected," astronomer Kristen Sellgren, with Ohio State University, told Discovery News.

From interstellar space, buckyballs apparently somehow migrated to star-forming regions, with some ending up in meteorites that fell to Earth.

"If I was FedEx of space, I'd want buckyballs for packaging. With a buckyball you can put something all the way inside, but it has to be small," Sellgren said.

Stanghellini's research appears in this week's Astrophysical Journal Letters. Sellgren's study was published in the journal's Oct. 10 edition.

Re: Bushels of Buckyballs Found in Space

PostPosted: Sun Oct 31, 2010 3:51 pm
by Wombaticus Rex
Ahhhhh.....best post of the day. Thank you for this brainfood.

Re: Bushels of Buckyballs Found in Space

PostPosted: Sun Oct 31, 2010 4:41 pm
by DoYouEverWonder
So instead of being made of star dust, we're just star gas?

Re: Bushels of Buckyballs Found in Space

PostPosted: Sun Oct 31, 2010 6:50 pm
by anothershamus
This explains the Wormhole machine from the movie Contact:

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Re: Bushels of Buckyballs Found in Space

PostPosted: Mon Mar 23, 2015 3:08 pm
by seemslikeadream
CAN BUCKYBALL ‘BOMBS’ BLOW UP CANCER?
UNIVERSITY OF SOUTHERN CALIFORNIA

Posted by Robert Perkins-USC on March 19, 2015

In 1996, a trio of scientists won the Nobel Prize for Chemistry for their discovery of Buckminsterfullerene–soccer-ball-shaped spheres of 60 joined carbon atoms that exhibit special physical properties.

Now, 20 years later, scientists have figured out how to turn them into buckybombs.

These nanoscale explosives show potential for use in fighting cancer, with the hope that they could one day target and eliminate cancer at the cellular level–triggering tiny explosions that kill cancer cells with minimal impact on surrounding tissue.

“Future applications would probably use other types of carbon structures–such as carbon nanotubes, but we started with buckyballs because they’re very stable, and a lot is known about them,” says Oleg V. Prezhdo, professor of chemistry at the University of Southern California and corresponding author of a paper on the new explosives published in the Journal of Physical Chemistry.

Carbon nanotubes, close relatives of buckyballs, are used already to treat cancer. They can be accumulated in cancer cells and heated up by a laser, which penetrates through surrounding tissues without affecting them, and targets carbon nanotubes directly.

Modifying carbon nanotubes the same way as the buckybombs will make the cancer treatment more efficient–reducing the amount of treatment needed, Prezhdo says.

To build the miniature explosives, Prezhdo and his colleagues attached 12 nitrous oxide molecules to a single buckyball and then heated it. Within picoseconds, the buckyball disintegrated–increasing temperature by thousands of degrees in a controlled explosion.

The source of the explosion’s power is the breaking of powerful carbon bonds, which snap apart to bond with oxygen from the nitrous oxide, resulting in the creation of carbon dioxide, Prezhdo says.

Prezhdo collaborated with co-corresponding author Vitaly V. Chaban, who was at USC when the research was completed and is now at the Universidade Federal de São Paulo in Brazil with fellow co-corresponding author Eudes Eterno Fileti.

The São Paulo Research Foundation, the Brazilian National Council for Scientific and Technological Development, the US Department of Energy, and the Russian Science Foundation funded the study.

Re: Bushels of Buckyballs Found in Space

PostPosted: Tue Mar 24, 2015 10:00 am
by Squatterman
"That's no bucky ball..."

Re: Bushels of Buckyballs Found in Space

PostPosted: Tue Mar 24, 2015 10:44 am
by Twyla LaSarc
Where I grew up there were a few buckyball houses. As this was the same state as his college tenure (SIU), the original builders probably attended his classes when young and impressionable.

I always thought they were cool and always wanted to live in one. They turn up from time to time in 'cabin porn' sites.

Re: Bushels of Buckyballs Found in Space

PostPosted: Tue Mar 24, 2015 11:20 am
by slomo
Twyla LaSarc » 24 Mar 2015 06:44 wrote:They turn up from time to time in 'cabin porn' sites.

I read that first as "carbon porn", and immediately imagined a website where viewers lasciviously admire fullerene configurations.

Re: Bushels of Buckyballs Found in Space

PostPosted: Tue Mar 24, 2015 8:55 pm
by Twyla LaSarc
slomo » Tue Mar 24, 2015 8:20 am wrote:
Twyla LaSarc » 24 Mar 2015 06:44 wrote:They turn up from time to time in 'cabin porn' sites.

I read that first as "carbon porn", and immediately imagined a website where viewers lasciviously admire fullerene configurations.


LOL!

Carbon porn, works as well. They don't call them Buckyballs for nothing.

Thanks for the laugh, I needed a good one today. :thumbsup

Re: Bushels of Buckyballs Found in Space

PostPosted: Thu Sep 08, 2022 12:34 am
by cptmarginal
Human dietary intake of buckminsterfullerene in olive oil has got to be one of the weirdest things I've heard of in a while.

"Buckminsterfullerene is a type of fullerene with the formula C60. It has a cage-like fused-ring structure (truncated icosahedron) made of twenty hexagons and twelve pentagons, and resembles a soccer ball."

https://doi.org/10.1089/rej.2020.2403

Effect of Long-Term Treatment with C60 Fullerenes on the Lifespan and Health Status of CBA/Ca Mice

Published Online:20 Oct 2021

Abstract

Several studies claimed C60 fullerenes as a prospective geroprotector drug due to their ability to capture free radicals effectively and caused a profound interest in C60 in life extension communities. Multiple additives are already sold for human consumption despite a small body of evidence supporting the beneficial effects of fullerenes on the lifespan. To test the effect of C60 fullerenes on lifespan and healthspan, we administered C60 fullerenes dissolved in virgin olive oil orally to 10–12 months old CBA/Ca mice of both genders for 7 months and assessed their survival. To uncover C60 and virgin olive effects, we established two control groups: mice treated with virgin olive oil (vehicle) and mice treated with drinking water. To measure healthspan, we conducted daily monitoring of health condition and lethality and monthly bodyweight measurements. We also assessed physical activity, glucose metabolism, and hematological parameters every 3 months. We did not observe health deterioration in the animals treated with C60 compared with the control groups. Treatment of mice with C60 fullerenes resulted in an increased lifespan of males and females compared with the olive oil-treated animals. The lifespan of C60-treated mice was similar to the mice treated with water. These results suggest that the lifespan-extending effect in C60-treated mice appears due to the protective effect of fullerenes in opposition to the negative effect of olive oil in CBA/Ca mice.

...

In the previous report of Baati et al.,10 treatment of rats with C60 resulted in a pronounced lifespan extension. We did not find a strain-specific lifespan extension effect of C60-treatment in our investigation, which contradicts the above-mentioned results. What can be the reason? Different sensitivity of mice and rats to the effects of toxic/medicinal substances may be one of the possible explanations. Rats are more sensitive to many substances, and they need a lower dose to get a significant biological effect than mice.21 Mice and rats express different cytochrome isoforms, which may affect the drug metabolism,22 and show species-specific differences in biodistribution and excretion of gold nanoparticles.23 Therefore, the insufficient dose may explain such a low efficiency of C60 lifespan prolongation observed in our study, although it is just a suggestion and requires further experimental verification.


C60 fullerene shows up in so many diverse applications that it boggles the mind.

https://doi.org/10.1002/cphc.202200226

The Hunter Falls Prey: Photoinduced Oxidation of C60 in Inclusion Complex with Perfluorocycloparaphenylene

First published: 19 May 2022

Abstract

Quantum-chemical modeling of photoinduced electron transfer processes in PF[10]CPP⊃C60 reveals that well-known electron acceptor C60 can donate electron to fully fluorinated carbon nanoring. This charge separation process is thermodynamically favorable and significantly faster than charge recombination.

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...

The importance of converting sunlight into electricity and chemical fuels cannot be overstated. A lot of attention and efforts have been paid to design and prepare model compounds that mimic natural photosynthetic systems.1 Generation of long-lived charge-separated (CS) states with a high quantum yield and a long distance between radical ions to prevent their recombination is of key essence for such donor-acceptor systems.2 Since their discovery in 1985,3 fullerenes have attracted considerable attention as efficient electron acceptors in photovoltaics due to their properties such as a narrow HOMO–LUMO gap and good electron transportability.


https://doi.org/10.3847/1538-4357/ac75d5

A Theoretical Study of Infrared Spectra of Highly Positively Charged C60 Fullerenes and Their Relevance to Observed UIE Features

Published 2022 July 27

...

6.2. Aromatic Little Bucky

Nicknamed by us little bucky, ${{\rm{C}}}_{60}^{10+}$ has also been generated under laboratory conditions and has been detected in the gas phase. It has been the subject of numerous theoretical studies (Poater & Sola 2011; Chen et al. 2012). The latest theoretical assessments on the electronic structure of this special species demonstrated its highly aromatic character, contrary to the anti-aromaticity of neutral C60 (Chen et al. 2012). Generally, aromaticity (with its all controversial aspects) makes a significant contribution to the formation or destruction paths and to increase the lifetime of molecular systems under different physical conditions. One may ask if neutral fullerene C60 itself has been formed in detectable amounts in astronomical sources, despite its anti-aromaticity character, then why should not little bucky, with its highly aromatic character, also be detected given the right conditions?

Considering the theoretically allowed high-level ionizations of neutral C60 and their feasibility to occur in extreme astrophysical environments, it is worth searching for little bucky footprints from space.


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That's pretty interesting but there is so much research being done on health effects of C60:

Water-Soluble, Alanine-Modified Fullerene C60 Promotes the Proliferation and Neuronal Differentiation of Neural Stem Cells - 20 May 2022

"In this study, a water-soluble fullerene C60 derivative bearing alanine was synthesized [with] high potential to be applied as a scaffold with neural stem cells for regeneration in nerve tissue engineering for diseases related to the nervous system"

Effect of C60 Fullerene on Recovery of Muscle Soleus in Rats after Atrophy Induced by Achillotenotomy - 23 February 2022

"The obtained results indicate a promising prospect for C60 fullerene use as a powerful antioxidant for reducing and correcting pathological conditions of the muscular system arising from skeletal muscle atrophy."

Progress in Antiviral Fullerene Research - 24 July 2022

"Unlike traditional small molecule drugs, fullerene is an all-carbon nanomolecule with a spherical cage structure. Fullerene exhibits high levels of antiviral activity, inhibiting virus replication in vitro and in vivo."

Application of Fullerenes as Photosensitizers for Antimicrobial Photodynamic Inactivation: A Review - 14 July 2022

"ROS clearance ability in the dark makes fullerenes promising candidates as additives to wound dressings and dental implants, with both antibacterial & wound healing promotion abilities."

Functional Gadofullerene Nanoparticles Trigger Robust Cancer Immunotherapy Based on Rebuilding an Immunosuppressive Tumor Microenvironment - May 14, 2020

"Fullerene C60 activates tumor immunity by polarizing tumor-associated macrophages and combines with immune checkpoint inhibitors (PD-L1 monoclonal antibody) to achieve efficient tumor immunotherapy"

Regarding that last study, see my post on immune checkpoint blockade therapy.

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Re: Bushels of Buckyballs Found in Space

PostPosted: Thu Sep 08, 2022 12:37 am
by cptmarginal
Progress in Antiviral Fullerene Research - 24 July 2022

"Unlike traditional small molecule drugs, fullerene is an all-carbon nanomolecule with a spherical cage structure. Fullerene exhibits high levels of antiviral activity, inhibiting virus replication in vitro and in vivo."


Structure diagram of glycofullerene

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